Publications
33. HC Schunk, MJ Austin, BZ Taha, MS McClellan, LJ Suggs, AM Rosales.* “Oxidative degradation of sequence-defined peptoid oligomers,” Molecular Systems Design & Engineering, 8(1): 92-104 (2023).
32. LD Morton, DA Castilla-Casadiego, AC Palmer, AM Rosales.* “Crosslinker structure modulates bulk mechanical properties and dictates hMSC behavior on hyaluronic acid hydrogels,” Acta Biomaterialia, 155: 258-270 (2023).
31. MJ Austin, H Schunk, C Watkins, N Ling, J Chauvin, L Morton, AM Rosales.* “Fluorescent Peptomer Substrates for Differential Degradation by Metalloproteases,” Biomacromolecules, 23(11): 4909-4923 (2022).
30. AM Green, S Kadulkar, ZM Sherman, TM Fitzsimons, CK Ofosu, J Yan, D Zhao, J Ilavsky, AM Rosales, BA Helms, V Ganesan, TM Truskett, DJ Milliron. “Depletion-Driven Assembly of Polymer-Coated Nanocrystals,” Journal of Physical Chemistry C, 126(45): 19507-19518 (2022).
29. K Chung, KN Halwachs, P Lu, K Sun, H Silva, AM Rosales, ZA Page. “Rapid hydrogel formation via tandem visible light photouncaging and bioorthogonal ligation,” Cell Reports Physical Science, 3(12) (2022).
28. DA Castilla-Casadiego, KA Miranda-Muñoz, JL Roberts, AD Crowell, D Gonzalez-Nino, D Choudhury, FO Aparicio-Solis, SL Servoss, AM Rosales, G Prinz, M Zou, Y Zhang, J Coetzee, LF Greenlee, J Powell, J Almodovar. “Biodegradable microneedle patch for delivery of meloxicam for managing pain in cattle,” PloS one, 17(8), e0272169 (2022).
27. A Hillsley, M Santoso, SM Engels, KN Halwachs, LM Contreras, AM Rosales.* “A strategy to quantify myofibroblast activation on a continuous spectrum,” Scientific Reports, 12: 12239 (2022).
26. M Haseli, DA Castilla-Casadiego, L Pinzon-Herrera, A Hillsley, KA Miranda-Muñoz, S Sivaraman, AM Rosales, R Rao, J Almodovar. “Immunomodulatory functions of human mesenchymal stromal cells are enhanced when cultured on HEP/COL multilayers supplemented with interferon-gamma,” Materials Today Bio, 13: 100194 (2022).
25. TM FitzSimons, EV Anslyn, AM Rosales.* “Effect of pH on the Properties of Hydrogels Cross-Linked via Dynamic Thia-Michael Addition Bonds,” ACS Polymers Au, 2(2): 129-136 (2021).
24. A Hillsley, JE Santos, AM Rosales.* “A deep learning approach to identify and segment alpha-smooth muscle actin stress fiber positive cells,” Scientific Reports, 11: 21855 (2021).
23. MK Rausch, SH Parekh, B Dortdivanlioglu, AM Rosales. “Synthetic hydrogels as blood clot mimicking wound healing materials,” Progress in Biomedical Engineering, 3(4): 042006 (2021).
22. CO Crosby, A Hillsley, S Kumar, SH Parekh, AM Rosales, J Zoldan. “Phototunable interpenetrating polymer network hydrogels to stimulate the vasculogenesis of stem cell-derived endothelial progenitors,” Acta Biomaterialia, 122: 133-144 (2021).
21. DS Hernandez, HC Schunk, KM Shankar, AM Rosales, LJ Suggs. “Poly-D-lysine coated nanoparticles to identify pro-inflammatory macrophages,” Nanoscale Advances, 2: 3849-3857 (2020).
20. AA Burkey, A Hillsley, DT Harris, JR Baltzegar, DY Zhang, WW Sprague, AM Rosales,* NA Lynd.* “Mechanism of polymer-mediated cryopreservation using poly(methyl glycidyl sulfoxide),” Biomacromolecules, 21(8): 3047-3055 (2020).
19. LD Morton, AV Hillsley, MJ Austin, AM Rosales.* “Tuning Hydrogel Properties with Sequence-Defined, Non-Natural Peptoid Crosslinkers,” Journal of Materials Chemistry B, 8: 6925-6933 (2020).
18. HC Schunk, DS Hernandez, MJ Austin, KS Dhada, AM Rosales,* LJ Suggs.* “Assessing the Range of Enzymatic and Oxidative Tunability for Biosensor Design.” Journal of Materials Chemistry B, 8: 3460-3487 (2020).
17. TM FitzSimons, F Oentoro, TV Shanbhag, EV Anslyn, AM Rosales.* "Preferential Control of Forward Reaction Kinetics in Hydrogels Crosslinked with Reversible Conjugate Additions," Macromolecules, 53(10): 3738-3746 (2020).
16. AJ Graham, CM Dundas, A Hillsley, DS Kasprak, AM Rosales,* BK Keitz.* "Genetic control of radical crosslinking in a semi-synthetic hydrogel," ACS Biomaterials Science and Engineering, 6(3): 1375-1386 (2020).
15. MJ Austin, AM Rosales.* “Tunable biomaterials from synthetic, sequence-controlled polymers.” Biomaterials Science, 7: 490-505 (2019).
14. EC Davidson, AM Rosales, AL Patterson, B Russ, B Yu, RN Zuckermann, RA Segalman. "Impact of Helical Chain Shape in Sequence-Defined Polymers on Polypeptoid Block Copolymer Self-Assembly," Macromolecules, 51(5): 2089-2098 (2018).DOI: 10.1021/acs.macromol.8b00055
13. AM Rosales, CB Rodell, MH Chen, MG Morrow, KS Anseth, JA Burdick. "Reversible Control of Network Properties in Azobenzene-Containing Hyaluronic Acid-Based Hydrogels," Bioconjugate Chemistry, 29(4): 905-913 (2018). DOI: 10.1021/acs.bioconjchem.7b00802
12. BA Aguado, JC Grim, AM Rosales, JJ Watson-Capps, KS Anseth. "Engineering Precision Biomaterials for Personalized Medicine." Science Translational Medicine, 10: (2018). DOI: 10.1126/scitranslmed.aam8645
11. AM Rosales, SL Vega, FW DelRio, JA Burdick, KS Anseth. "Hydrogels with reversible mechanics to probe dynamic cell microenvironments," Angewandte Chemie, 129(40):12300-12304. DOI: 10.1002/anie.201705684
10. AM Rosales, KS Anseth. "The design of reversible hydrogels to capture extracellular matrix dynamics," Nature Reviews Materials, 1: 15012 (2016). DOI:10.1038/natrevmats.2015.12
9. EM Nehls, AM Rosales, KS Anseth. "Enhanced user-control of small molecule drug release from a poly (ethylene glycol) hydrogel via azobenzene/cyclodextrin complex tethers," Journal of Materials Chemistry B, 4(6): 1035-1039 (2016). DOI: 10.1039/C5TB02004B
8. AM Rosales, KM Mabry, EM Nehls, KS Anseth. "Photoresponsive elastic properties of azobenzene-containing poly(ethylene-glycol)-based hydrogels," Biomacromolecules, 16(3): 798-806 (2015). DOI: 10.1021/bm501710e
7. AM Rosales, RA Segalman, RN Zuckermann. "Polypeptoids: a model system to study the effect of monomer sequence on polymer properties and self-assembly," Soft Matter, 9(35): 8400-8414 (2013). DOI: 10.1039/C3SM51421H
6. HK Murnen, AM Rosales, AV Dobrynin, RN Zuckermann, RA Segalman. "Persistence length of polyelectrolytes with precisely located charges," Soft Matter, 9(1): 90-98 (2012). DOI: 10.1039/C2SM26849C
5. AM Rosales, BL McCulloch, RN Zuckermann, RA Segalman. "Tunable phase behavior of polystyrene–polypeptoid block copolymers," Macromolecules, 45(15): 6027-6035 (2012). DOI: 10.1021/ma300625b
4. AM Rosales, HK Murnen, SR Kline, RN Zuckermann, RA Segalman. "Determination of the persistence length of helical and non-helical polypeptoids in solution," Soft Matter, 8(13): 3673-3680 (2012). DOI: 10.1039/C2SM07092H
3. HK Murnen, AM Rosales, JN Jaworski, RA Segalman, RN Zuckermann. "Hierarchical self-assembly of a biomimetic diblock copolypeptoid into homochiral superhelices," Journal of the American Chemical Society, 132(45): 16112-16119 (2010). DOI: 10.1021/ja106340f
2. AM Rosales, HK Murnen, RN Zuckermann, RA Segalman. "Control of crystallization and melting behavior in sequence specific polypeptoids," Macromolecules, 43(13): 5627-5636 (2010). DOI: 10.1021/ma1002563
1. JB Thomas, JH Tingsanchali, AM Rosales, CM Creecy, JW McGinity, NA Peppas. "Dynamics of poly (ethylene glycol)-tethered, pH responsive networks," Polymer 48(17): 5042-5048 (2007). DOI: 10.1016/j.polymer.2007.06.035