Publications

40. DA Castilla-Casadiego, DH Loh, A Pineda-Hernandez, AM Rosales. “Stimuli-Responsive Substrates to Control the Immunomodulatory Potential of Stromal Cells.” Biomacromolecules (2024).

39. A.J. Graham*, G. Partipilo*, C.M. Dundas, I.E. Miniel Mahfoud, K.N. Halwachs, A.J. Holwerda, T.R. Simmons, T. FitzSimons, S.M. Coleman, R. Rinehart, D. Chiu, A.E. Tyndall, K.C. Sajbel, A.M. Rosales, B.K. Keitz. “Transcriptional regulation of living materials via extracellular electron transfer.” Nature Chemical Biology, 1-12 (2024).

38. DA Castilla-Casadiego, LD Morton, DH Loh, A Pineda-Hernandez, AP Chavda, F Garcia, AM Rosales. “Peptoid-cross-linked hydrogel stiffness modulates human mesenchymal stromal cell immunoregulatory potential in the presence of interferon-gamma.” Macromolecular Bioscience, 2400111 (2024). DOI: 10.1002/mabi.202400111

37. K Thapa, TM FitzSimons, MU Otakpor, MM Siller, AD Crowell, JE Zepeda, E Torres, LN Roe, J Arts, AM Rosales, T Betancourt. “Photothermal modulation of dynamic covalent poly(ethylene glycol)/PEDOT composite hydrogels for on-demand drug delivery.” ACS Applied Materials & Interfaces, 15(45): 52180-52196 (2023). DOI: 10.1021/acsami/3c11288

36. AD Crowell, TM FitzSimons, EV Anslyn, KM Schultz, AM Rosales. “Shear thickening behavior in injectable tetra-PEG hydrogels cross-linked via dynamic thia-Michael addition bonds.” Macromolecules, 56(19): 7795-7807 (2023). DOI: 10.1021/acs.macromol.3c00780

35. TM FitzSimons, AM Rosales. “Leveraging mechanistic insight to design dynamic hydrogels.” Chem, 9(8): 2051-2053 (2023). DOI: 10.1016/j.chempr.2023.07.019

34. MJ Austin, HC Schunk, N Ling, AM Rosales. “Peptomer substrates for quantitative pattern-recognition sensing of proteases,” Chemical Communications, 59(12): 1685-1688 (2023). DOI: 10.1039/D2CC06587H

33. HC Schunk, MJ Austin, BZ Taha, MS McClellan, LJ Suggs, AM Rosales.* “Oxidative degradation of sequence-defined peptoid oligomers,” Molecular Systems Design & Engineering, 8(1): 92-104 (2023).

32. LD Morton, DA Castilla-Casadiego, AC Palmer, AM Rosales.* “Crosslinker structure modulates bulk mechanical properties and dictates hMSC behavior on hyaluronic acid hydrogels,” Acta Biomaterialia, 155: 258-270 (2023).

31. MJ Austin, H Schunk, C Watkins, N Ling, J Chauvin, L Morton, AM Rosales.* “Fluorescent Peptomer Substrates for Differential Degradation by Metalloproteases,” Biomacromolecules, 23(11): 4909-4923 (2022).

30. AM Green, S Kadulkar, ZM Sherman, TM Fitzsimons, CK Ofosu, J Yan, D Zhao, J Ilavsky, AM Rosales, BA Helms, V Ganesan, TM Truskett, DJ Milliron. “Depletion-Driven Assembly of Polymer-Coated Nanocrystals,” Journal of Physical Chemistry C, 126(45): 19507-19518 (2022).

29. K Chung, KN Halwachs, P Lu, K Sun, H Silva, AM Rosales, ZA Page. “Rapid hydrogel formation via tandem visible light photouncaging and bioorthogonal ligation,” Cell Reports Physical Science, 3(12) (2022).

28. DA Castilla-Casadiego, KA Miranda-Muñoz, JL Roberts, AD Crowell, D Gonzalez-Nino, D Choudhury, FO Aparicio-Solis, SL Servoss, AM Rosales, G Prinz, M Zou, Y Zhang, J Coetzee, LF Greenlee, J Powell, J Almodovar. “Biodegradable microneedle patch for delivery of meloxicam for managing pain in cattle,” PloS one, 17(8), e0272169 (2022).

27. A Hillsley, M Santoso, SM Engels, KN Halwachs, LM Contreras, AM Rosales.* “A strategy to quantify myofibroblast activation on a continuous spectrum,” Scientific Reports, 12: 12239 (2022).

26. M Haseli, DA Castilla-Casadiego, L Pinzon-Herrera, A Hillsley, KA Miranda-Muñoz, S Sivaraman, AM Rosales, R Rao, J Almodovar. “Immunomodulatory functions of human mesenchymal stromal cells are enhanced when cultured on HEP/COL multilayers supplemented with interferon-gamma,” Materials Today Bio, 13: 100194 (2022).

25. TM FitzSimons, EV Anslyn, AM Rosales.* “Effect of pH on the Properties of Hydrogels Cross-Linked via Dynamic Thia-Michael Addition Bonds,” ACS Polymers Au, 2(2): 129-136 (2021).

24. A Hillsley, JE Santos, AM Rosales.* “A deep learning approach to identify and segment alpha-smooth muscle actin stress fiber positive cells,” Scientific Reports, 11: 21855 (2021).

23. MK Rausch, SH Parekh, B Dortdivanlioglu, AM Rosales. “Synthetic hydrogels as blood clot mimicking wound healing materials,” Progress in Biomedical Engineering, 3(4): 042006 (2021).

22. CO Crosby, A Hillsley, S Kumar, SH Parekh, AM Rosales, J Zoldan. “Phototunable interpenetrating polymer network hydrogels to stimulate the vasculogenesis of stem cell-derived endothelial progenitors,” Acta Biomaterialia, 122: 133-144 (2021).

21. DS Hernandez, HC Schunk, KM Shankar, AM Rosales, LJ Suggs. “Poly-D-lysine coated nanoparticles to identify pro-inflammatory macrophages,” Nanoscale Advances, 2: 3849-3857 (2020).

20. AA Burkey, A Hillsley, DT Harris, JR Baltzegar, DY Zhang, WW Sprague, AM Rosales,* NA Lynd.* “Mechanism of polymer-mediated cryopreservation using poly(methyl glycidyl sulfoxide),” Biomacromolecules, 21(8): 3047-3055 (2020).

19. LD Morton, AV Hillsley, MJ Austin, AM Rosales.* “Tuning Hydrogel Properties with Sequence-Defined, Non-Natural Peptoid Crosslinkers,” Journal of Materials Chemistry B, 8: 6925-6933 (2020).

18. HC Schunk, DS Hernandez, MJ Austin, KS Dhada, AM Rosales,* LJ Suggs.* “Assessing the Range of Enzymatic and Oxidative Tunability for Biosensor Design.” Journal of Materials Chemistry B, 8: 3460-3487 (2020).

17. TM FitzSimons, F Oentoro, TV Shanbhag, EV Anslyn, AM Rosales.* "Preferential Control of Forward Reaction Kinetics in Hydrogels Crosslinked with Reversible Conjugate Additions," Macromolecules, 53(10): 3738-3746 (2020).

16. AJ Graham, CM Dundas, A Hillsley, DS Kasprak, AM Rosales,* BK Keitz.* "Genetic control of radical crosslinking in a semi-synthetic hydrogel," ACS Biomaterials Science and Engineering, 6(3): 1375-1386 (2020).

15. MJ Austin, AM Rosales.* “Tunable biomaterials from synthetic, sequence-controlled polymers.” Biomaterials Science, 7: 490-505 (2019).

14. EC Davidson, AM Rosales, AL Patterson, B Russ, B Yu, RN Zuckermann, RA Segalman. "Impact of Helical Chain Shape in Sequence-Defined Polymers on Polypeptoid Block Copolymer Self-Assembly," Macromolecules, 51(5): 2089-2098 (2018).DOI: 10.1021/acs.macromol.8b00055

13. AM Rosales, CB Rodell, MH Chen, MG Morrow, KS Anseth, JA Burdick. "Reversible Control of Network Properties in Azobenzene-Containing Hyaluronic Acid-Based Hydrogels," Bioconjugate Chemistry, 29(4): 905-913 (2018). DOI: 10.1021/acs.bioconjchem.7b00802

12. BA Aguado, JC Grim, AM Rosales, JJ Watson-Capps, KS Anseth. "Engineering Precision Biomaterials for Personalized Medicine." Science Translational Medicine, 10: (2018). DOI: 10.1126/scitranslmed.aam8645

11. AM Rosales, SL Vega, FW DelRio, JA Burdick, KS Anseth. "Hydrogels with reversible mechanics to probe dynamic cell microenvironments," Angewandte Chemie, 129(40):12300-12304. DOI: 10.1002/anie.201705684

10. AM Rosales, KS Anseth. "The design of reversible hydrogels to capture extracellular matrix dynamics," Nature Reviews Materials, 1: 15012 (2016). DOI:10.1038/natrevmats.2015.12

9. EM Nehls, AM Rosales, KS Anseth. "Enhanced user-control of small molecule drug release from a poly (ethylene glycol) hydrogel via azobenzene/cyclodextrin complex tethers," Journal of Materials Chemistry B, 4(6): 1035-1039 (2016). DOI: 10.1039/C5TB02004B

8. AM Rosales, KM Mabry, EM Nehls, KS Anseth. "Photoresponsive elastic properties of azobenzene-containing poly(ethylene-glycol)-based hydrogels," Biomacromolecules, 16(3): 798-806 (2015). DOI: 10.1021/bm501710e

7. AM Rosales, RA Segalman, RN Zuckermann. "Polypeptoids: a model system to study the effect of monomer sequence on polymer properties and self-assembly," Soft Matter, 9(35): 8400-8414 (2013). DOI: 10.1039/C3SM51421H

6. HK Murnen, AM Rosales, AV Dobrynin, RN Zuckermann, RA Segalman. "Persistence length of polyelectrolytes with precisely located charges," Soft Matter, 9(1): 90-98 (2012). DOI: 10.1039/C2SM26849C

5. AM Rosales, BL McCulloch, RN Zuckermann, RA Segalman. "Tunable phase behavior of polystyrene–polypeptoid block copolymers," Macromolecules, 45(15): 6027-6035 (2012). DOI: 10.1021/ma300625b

4. AM Rosales, HK Murnen, SR Kline, RN Zuckermann, RA Segalman. "Determination of the persistence length of helical and non-helical polypeptoids in solution," Soft Matter, 8(13): 3673-3680 (2012). DOI: 10.1039/C2SM07092H

3. HK Murnen, AM Rosales, JN Jaworski, RA Segalman, RN Zuckermann. "Hierarchical self-assembly of a biomimetic diblock copolypeptoid into homochiral superhelices," Journal of the American Chemical Society, 132(45): 16112-16119 (2010). DOI: 10.1021/ja106340f

2. AM Rosales, HK Murnen, RN Zuckermann, RA Segalman. "Control of crystallization and melting behavior in sequence specific polypeptoids," Macromolecules, 43(13): 5627-5636 (2010). DOI: 10.1021/ma1002563

1. JB Thomas, JH Tingsanchali, AM Rosales, CM Creecy, JW McGinity, NA Peppas. "Dynamics of poly (ethylene glycol)-tethered, pH responsive networks," Polymer 48(17): 5042-5048 (2007). DOI: 10.1016/j.polymer.2007.06.035